Chemistry
Atomic structure, chemical bonding, materials science, and the chemistry behind semiconductors, conductors, and batteries.
Atomic Structure
Fundamentals
Atom: nucleus (protons + neutrons) + electron cloud
Element: defined by number of protons (atomic number Z)
Subatomic particles:
Proton: +1 charge, mass ≈ 1 amu, in nucleus
Neutron: 0 charge, mass ≈ 1 amu, in nucleus
Electron: -1 charge, mass ≈ 1/1836 amu, in orbitals
Isotopes: same element, different neutron count
Carbon-12: 6 protons, 6 neutrons
Carbon-14: 6 protons, 8 neutrons (radioactive)
Electron configuration
Shells: K(2) L(8) M(18) N(32)
Orbitals: s(2) p(6) d(10) f(14)
Silicon (Z=14): 1s^2 2s^2 2p^6 3s^2 3p^2
4 valence electrons → semiconductor
Doping with P (5 valence) → n-type
Doping with B (3 valence) → p-type
Chemical Bonding
Bond types
Ionic: electron transfer (NaCl — Na gives e- to Cl)
Metals + nonmetals
High melting point, conducts when dissolved
Covalent: electron sharing (H2O, SiO2)
Nonmetal + nonmetal
Can be polar (unequal sharing) or nonpolar
Metallic: electron sea model (Cu, Al, Fe)
Metal atoms share delocalized electrons
Conducts electricity, malleable, lustrous
Van der Waals: weak intermolecular forces
Temporary dipoles
Why geckos stick to walls
Relevance to hardware
Silicon: covalent crystal, semiconductor backbone
Copper: metallic bonding, excellent conductor (PCB traces)
Solder: Sn-Pb or Sn-Ag-Cu alloys (metallic)
Thermal paste: silicone + metal oxide (fills air gaps)
Li-ion battery: lithium ions move between electrodes
Anode: graphite (LiC6)
Cathode: LiCoO2 or LiFePO4
Electrolyte: organic solvent with Li salt
Reactions and Stoichiometry
Balancing equations
Conservation of mass: atoms in = atoms out
Example (rust):
4Fe + 3O2 → 2Fe2O3
Mole: 6.022 × 10^23 particles (Avogadro's number)
Molar mass: mass of one mole in grams
H2O: 2(1.008) + 16.00 = 18.02 g/mol
pH scale: measures hydrogen ion concentration
pH = -log_10[H+]
pH 7 = neutral
pH < 7 = acidic (battery acid ≈ 1)
pH > 7 = basic (bleach ≈ 13)
Materials Science
Conductors, insulators, semiconductors
Conductor: low resistivity, free electrons (Cu, Ag, Au)
ρ_Cu ≈ 1.7 × 10^-8 Ω·m
Insulator: high resistivity, no free carriers (glass, rubber)
ρ_glass ≈ 10^12 Ω·m
Semiconductor: middle ground, controllable (Si, Ge, GaAs)
ρ_Si ≈ 640 Ω·m (intrinsic)
Doping changes resistivity by orders of magnitude
Superconductor: zero resistance below critical temperature
Tc for YBCO ≈ 93 K (-180°C)
See Also
-
Electronics — semiconductor physics builds on chemistry
-
Physics — electrical properties of materials